The Mystery of the Boiled Batteries

While debugging a strange battery failure in a manufacturing process, [Josh] discovered a new (to us) LiPo battery failure mode.

Different battery chemistries react differently to temperature. We’ve used lithium exclusively in high-altitude ballooning, for instance, because of their decent performance when cold. Lithium batteries generally don’t like high temperatures, on the other hand, but besides the risk of bursting into flames, we had no idea that heat could kill them. When the battery’s voltage is already low, though, it turns out it can.

[Josh]’s process required molding plastic with the battery inside, and this meant heating the batteries up. After the fact, he noticed an unreasonably high failure rate in the batteries, and decided to test them out. He put the batteries, each in a different initial charge, into a plastic bag and tortured them all with ice and fire. (OK, boiling water.)

When the batteries got hot, their voltage sagged a little bit, but they recovered afterwards. And while the voltage sagged a little bit more for the batteries with lower initial charge, that’s nothing compared to the complete failure of the battery that entered the hot water with under 1V on it — see they yellow line in the graphs.

There’s a million ways to kill a battery, and lithium batteries are known not to like being completely discharged, but it looks like the combination of deep discharge and heat is entirely deadly. Now you know.

Filed under: chemistry hacks